If you own the original game discs and wish to emulate the console experience, look to modern emulators rather than PS2 software:
Available digitally via the Microsoft Store. Legitimate Emulation Options marvel vs capcom 3 ps2 rom
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Alternatively, you can play PS2 games directly on your console. This requires using a modded PS2 to run games from a hard drive or using software exploits like Free McBoot, which allow you to launch homebrew applications and backup games. The search results will help gather details